2026-07-072026-07-07http://salesiana.dossiersoluciones.com/handle/123456789/138982We reveal the existence of systematic variations of isobaric fragility in different supercooled Lennard-Jones binary mixtures by performing molecular dynamics simulations. The connection between fragility and local structures in the bulk is analyzed by means of a Voronoi construction. We find that clusters of particles belonging to locally preferred structures form slow, long-lived domains, whose spatial extension increases by decreasing temperature. As a general rule, a more rapid growth, upon supercooling, of such domains is associated to a more pronounced super-Arrhenius behavior, hence to a larger fragility.14 pages, 14 figures, minor revisions, one figure addedStatistical MechanicsSoft Condensed MatterUnderstanding fragility in supercooled Lennard-Jones mixtures. I. Locally preferred structurestext