2026-07-072026-07-07http://salesiana.dossiersoluciones.com/handle/123456789/172727The heat theorem (i.e. the second law of thermodynamics or the existence of entropy) is a manifestation of a general property of hamiltonian mechanics and of the ergodic Hypothesis. In nonequilibrium thermodynamics of stationary states the chaotic hypothesis plays a similar role: it allows a unique determination of the probability distribution (called {\rm SRB} distribution on phase space providing the time averages of the observables. It also implies an expression for a few averages concrete enough to derive consequences of symmetry properties like the fluctuation theorem or to formulate a theory of coarse graining unifying the foundations of equilibrium and of nonequilibrium.Basis for the plenary talk at StatPhys23 (Genova July 2007)Statistical MechanicsFluctuation Theorem and Chaostext