2026-07-072026-07-07http://salesiana.dossiersoluciones.com/handle/123456789/107053We show that Rb_4C_60 transforms from its ambient pressure orientationally disordered tetragonal structure to an ordered orthorhombic structure (isostructural to Cs_4C_60) at or above 0.4 GPa. This opens the possibility of studying the previously observed metal-insulator transition under pressure in this narrow band system as a function of a continuous variable, rather than formulating distinct models for conducting and insulating fullerides. No such transition is observed in K_4C_60 to 2.0 GPa13 pages 4 figuresStrongly Correlated ElectronsMaterials Sciencetext